This recent all-acoustic collection of live Townes tracks is worth it for a gorgeous rendition of his immortal Waitin' Round To Die alone. He can't remember for the life of him where the posse drags him back to though and flufs the Muskogee line, which is actually kinda funny. Here goes.
Townes Van Zandt - Waitin' Round To Die (live)
Is there a sadder song in his oeuvre? Since you ask, oh yes there is... And it's quite possibly the saddest song ever in my book, full stop. The story of Caroline, daughter of a miner. "Seemed to me that sunshine walked beside her..." Take it away, maestro.
Townes Van Zandt - Tecumseh Valley (live)